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- W2044953405 abstract "Abstract A new complex, [Co2(C25H30N4)3](NO3)4·8H2O, has been synthesized and characterized by single crystal X-ray diffraction, ESI-MS spectroscopy, electronic absorption spectrum, and magnetic measurements. The cation of the complex contains two cobalt(II) atoms and three ligands (L), which twist around the Co(II)–Co(II) axis, leading to a dinuclear triple helix. Each cobalt(II) atom is six-coordinated with three Co–N (pyridyl) and three Co–N (N CH–) of three ligands (L), and attains a pseudo-octahedral coordination geometry. Magnetic measurements show that the complex is a high-spin species in the temperature range of 75–300 K." @default.
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- W2044953405 date "2001-01-01" @default.
- W2044953405 modified "2023-09-23" @default.
- W2044953405 title "Synthesis, structure and properties of a new dinuclear Co(II) triple-helical complex" @default.
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- W2044953405 doi "https://doi.org/10.1016/s0022-2860(00)00726-2" @default.
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