Matches in SemOpenAlex for { <https://semopenalex.org/work/W2044990669> ?p ?o ?g. }
- W2044990669 endingPage "1211" @default.
- W2044990669 startingPage "1195" @default.
- W2044990669 abstract "High-energy overtone photoacoustic spectroscopy of gas phase CHD3 (ΔvCH=5,6, and 7), CH2D2, CH3D, and CH4 (ΔvCH=6) is reported. The overtone and combination bands of CHD3 display partially resolved rotational structure with laser limited linewidths (∼0.5 cm−1). A combination sum analysis is used to generate excited state rotational constants B′. We present an analysis of the Fermi resonances of CHD3 which indicates strong interactions of the CH stretch with degenerate bending modes. The relative intensities of the Fermi interacting states are in agreement with those calculated from an analysis based on frequency shifts and a two or three level model. However, the rotational B′ constants are not explained by such simple models indicating further interactions with states as yet unobserved. An upper limit of 10 cm−1 is estimated for the splitting of the ‖6,0〉± local mode states for CH2D2, giving support to a description based on the local mode picture. For CH3D and CH4 the spectra are apparently congested by overlapping overtone and combination bands and perhaps other mechanisms not identified in this work. Generally, our results emphasize the importance of the interactions of CH stretching with CH bending motions." @default.
- W2044990669 created "2016-06-24" @default.
- W2044990669 creator A5031995089 @default.
- W2044990669 creator A5058067393 @default.
- W2044990669 creator A5077807260 @default.
- W2044990669 creator A5079496881 @default.
- W2044990669 date "1985-02-01" @default.
- W2044990669 modified "2023-09-23" @default.
- W2044990669 title "High-energy overtone spectroscopy of some deuterated methanes" @default.
- W2044990669 cites W1536112388 @default.
- W2044990669 cites W1645382123 @default.
- W2044990669 cites W1970781232 @default.
- W2044990669 cites W1977516232 @default.
- W2044990669 cites W1983186947 @default.
- W2044990669 cites W1983961773 @default.
- W2044990669 cites W1984012947 @default.
- W2044990669 cites W1986639751 @default.
- W2044990669 cites W1986904241 @default.
- W2044990669 cites W1991295713 @default.
- W2044990669 cites W1991962265 @default.
- W2044990669 cites W1992922226 @default.
- W2044990669 cites W2000163760 @default.
- W2044990669 cites W2007100348 @default.
- W2044990669 cites W2007589680 @default.
- W2044990669 cites W2009892517 @default.
- W2044990669 cites W2022057557 @default.
- W2044990669 cites W2030591847 @default.
- W2044990669 cites W2053753155 @default.
- W2044990669 cites W2065085548 @default.
- W2044990669 cites W2065868844 @default.
- W2044990669 cites W2066546437 @default.
- W2044990669 cites W2067960050 @default.
- W2044990669 cites W2069584387 @default.
- W2044990669 cites W2070780695 @default.
- W2044990669 cites W2073952805 @default.
- W2044990669 cites W2075444356 @default.
- W2044990669 cites W2078924963 @default.
- W2044990669 cites W2094137467 @default.
- W2044990669 cites W2103058519 @default.
- W2044990669 cites W2138217136 @default.
- W2044990669 cites W2152689268 @default.
- W2044990669 cites W2176419377 @default.
- W2044990669 cites W2329432665 @default.
- W2044990669 cites W2954919512 @default.
- W2044990669 doi "https://doi.org/10.1063/1.448493" @default.
- W2044990669 hasPublicationYear "1985" @default.
- W2044990669 type Work @default.
- W2044990669 sameAs 2044990669 @default.
- W2044990669 citedByCount "84" @default.
- W2044990669 countsByYear W20449906692013 @default.
- W2044990669 countsByYear W20449906692014 @default.
- W2044990669 countsByYear W20449906692018 @default.
- W2044990669 countsByYear W20449906692021 @default.
- W2044990669 crossrefType "journal-article" @default.
- W2044990669 hasAuthorship W2044990669A5031995089 @default.
- W2044990669 hasAuthorship W2044990669A5058067393 @default.
- W2044990669 hasAuthorship W2044990669A5077807260 @default.
- W2044990669 hasAuthorship W2044990669A5079496881 @default.
- W2044990669 hasBestOaLocation W20449906692 @default.
- W2044990669 hasConcept C121332964 @default.
- W2044990669 hasConcept C153642686 @default.
- W2044990669 hasConcept C169146920 @default.
- W2044990669 hasConcept C178790620 @default.
- W2044990669 hasConcept C181500209 @default.
- W2044990669 hasConcept C184779094 @default.
- W2044990669 hasConcept C185592680 @default.
- W2044990669 hasConcept C2776565987 @default.
- W2044990669 hasConcept C31100168 @default.
- W2044990669 hasConcept C32891209 @default.
- W2044990669 hasConcept C38615331 @default.
- W2044990669 hasConcept C41999313 @default.
- W2044990669 hasConcept C4839761 @default.
- W2044990669 hasConcept C58364064 @default.
- W2044990669 hasConcept C62520636 @default.
- W2044990669 hasConcept C72319582 @default.
- W2044990669 hasConceptScore W2044990669C121332964 @default.
- W2044990669 hasConceptScore W2044990669C153642686 @default.
- W2044990669 hasConceptScore W2044990669C169146920 @default.
- W2044990669 hasConceptScore W2044990669C178790620 @default.
- W2044990669 hasConceptScore W2044990669C181500209 @default.
- W2044990669 hasConceptScore W2044990669C184779094 @default.
- W2044990669 hasConceptScore W2044990669C185592680 @default.
- W2044990669 hasConceptScore W2044990669C2776565987 @default.
- W2044990669 hasConceptScore W2044990669C31100168 @default.
- W2044990669 hasConceptScore W2044990669C32891209 @default.
- W2044990669 hasConceptScore W2044990669C38615331 @default.
- W2044990669 hasConceptScore W2044990669C41999313 @default.
- W2044990669 hasConceptScore W2044990669C4839761 @default.
- W2044990669 hasConceptScore W2044990669C58364064 @default.
- W2044990669 hasConceptScore W2044990669C62520636 @default.
- W2044990669 hasConceptScore W2044990669C72319582 @default.
- W2044990669 hasIssue "3" @default.
- W2044990669 hasLocation W20449906691 @default.
- W2044990669 hasLocation W20449906692 @default.
- W2044990669 hasOpenAccess W2044990669 @default.
- W2044990669 hasPrimaryLocation W20449906691 @default.
- W2044990669 hasRelatedWork W1987110542 @default.
- W2044990669 hasRelatedWork W2020444659 @default.