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- W2044996489 abstract "Abstract The stereoselectivities in the reactions of diazomethane with various α- d -hexopyranosid-4-uloses are compared with those in Grignard reactions. The results support the hypothesis that the stereoselectivity of the diazomethane reaction is mainly controlled by the attractive, electrostatic force between the diazomethyl cation and a neighbouring, axial oxygen or the axial lone-pair electrons of O-5 in the transition state." @default.
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- W2044996489 date "1982-05-01" @default.
- W2044996489 modified "2023-09-27" @default.
- W2044996489 title "Stereoselectivities in the reactions of α-d-hexopyranosid-4-uloses with diazomethane" @default.
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- W2044996489 doi "https://doi.org/10.1016/s0008-6215(00)80685-0" @default.
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