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- W2044998843 abstract "Methylated β-cyclodextrin was used to complex the hydrophobic monomers n-propyl acrylate (1), n-butyl acrylate (2), n-pentyl acrylate (3), n-hexyl acrylate (4), and cyclohexyl acrylate (5) respectively yielding the corresponding water-soluble host/guest-complexes 1a−5a. The complexes were polymerized in water by free radical mechanism and the initial polymerization rates (v0) determined. We found that v0 increases as follows: 1a (12.5), 2a (27.5), 3a (44.2), 5a (49.4), 4a (75.8 × 10-6 mol·L-1·s-1). To investigate the influence of the hydrophobic character of the guest monomers on the reaction rate, the water solubilities of the uncomplexed monomers 1−5 were determined by HPLC measurements. It was generally shown that with increase of water solubility of the free monomers the initial reaction rate (v0) decreases significantly." @default.
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- W2044998843 date "2001-02-10" @default.
- W2044998843 modified "2023-10-17" @default.
- W2044998843 title "Cyclodextrins in Polymer Synthesis: Influence of Acrylate Side Groups on the Initial Rate of Radical Polymerization of Various Acrylate/Methylated β-cyclodextrin Complexes in Water" @default.
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- W2044998843 doi "https://doi.org/10.1021/ma0016533" @default.
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