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• W2045000478 abstract "The structure and stability of hydrogen bonds in alpha-chitin were investigated by (13)C solid-state NMR measurements at different temperatures. Splitting of the carbonyl carbon signal for alpha-chitin was interpreted as two types of hydrogen bonding; the peaks at 173.5 and 175.8 ppm were assigned, respectively, to a carbonyl carbon hydrogen bonded exclusively to the NH group and a carbonyl carbon hydrogen-bonded to both NH and C(6)-OH groups. Approximately 60% of carbonyl groups exclusively contributed to the intermolecular hydrogen bonding and ca. 40% of them to the combination of intermolecular and intramolecular hydrogen bonding. Internal rotation around the C(5)-C(6) bond was detected at 55 degrees C." @default.
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• W2045000478 date "2005-02-10" @default.
• W2045000478 modified "2023-10-10" @default.
• W2045000478 title "Hydrogen Bonding Structure and Stability of?-Chitin Studied by13C Solid-State NMR" @default.
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• W2045000478 doi "https://doi.org/10.1002/mabi.200400142" @default.
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