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- W2045001566 abstract "Inorganic polysulfide anions S n 2− and the related radical anions S n ·− play an important role in the redox reactions of elemental sulfur and therefore also in the geobiochemical sulfur cycle. This chapter describes the preparation of the solid polysulfides with up to eight sulfur atoms and univalent cations, as well as their solid state structures, vibrational spectra and their behavior in aqueous and non-aqueous solutions. In addition, the highly colored and reactive radical anions S n ·− with n = 2, 3, and 6 are discussed, some of which exist in equilibrium with the corresponding diamagnetic dianions." @default.
- W2045001566 created "2016-06-24" @default.
- W2045001566 creator A5006743048 @default.
- W2045001566 date "2012-02-24" @default.
- W2045001566 modified "2023-10-13" @default.
- W2045001566 title "Inorganic Polysulfides S n 2− and Radical Anions S n ·−" @default.
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- W2045001566 doi "https://doi.org/10.1007/b13183" @default.
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