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- W2045010143 abstract "Abstract The l‐dimethoxymethyl‐5,6‐dimethyldene‐7‐oxabicyclo[2.2.1]hept‐2‐ene ( 9 ) has been prepared. On treatment with Fe 2 (CO) 9 , the endocyclic double bond C(2)C(3) was coordinated first giving the corresponding exo ‐Fe(CO) 4 complex 10 . The latter reacted with Fe 2 (CO) 9 and afforded cis ‐heptacarbonyl‐μ‐[1 RS ,2 SR ,3 RS ,4 SR ,5 RS ,6 SR ‐2,3‐η: C 5,6, C ‐η‐(1‐(dimethoxymethyl)‐5,6‐dimethylidene‐7‐oxabicyclo[2.2.1]hept‐2‐ene)]diiron ( 11 ) as a major product. On heating, 11 underwent deoxygenation of the 7‐oxabicyclo[2.2.1]heptene moiety yielding tricarbonyl[ C ,5,6, C ‐η‐(1‐(dimethoxymethyl)‐5,6‐dimethylidenecyclohexa‐1,3‐diene)]iron ( 13 ). In MeOH, a concurrent, regioselective methoxycarbonylation was observed giving tricarbonyl[ C ,3,4, C ‐η‐(methyl 5‐(dimethoxymethyl)‐3,4‐dimethylidenecyclohexa‐1,5‐diene‐1‐carboxylate)]iron ( 14 ). Oxidative removal of the Fe(CO) 3 moiety in 13 and 14 did not afford the expected ortho ‐quinodimethane derivatives but led to CO insertions giving 2,3‐dihydro‐2‐oxo‐1 H indene‐4‐carbaldehyde ( 20 ) and methyl 7‐formyl‐2‐3‐dihydro‐2‐oxo‐l H ‐indene‐5‐carboxylate ( 21 ), respectively." @default.
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- W2045010143 date "1987-11-04" @default.
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- W2045010143 title "Ironcarbonyl Complexes of 5,6-Dimethylidene-7-oxabicyclo[2.2.1]hept-2-ene Derivatives. Synthesis of Substituted Tricarbonyl(<i>ortho</i>-quinodimethane)iron Complexes and 2-Indanones" @default.
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- W2045010143 doi "https://doi.org/10.1002/hlca.19870700715" @default.
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