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- W2045011775 abstract "The crystal structure of tristhiourea-cadmium sulphate, Cd(SC(NH2)2)3SO4, has been determined by three dimensional X-ray analysis. Crystals are triclinic (P1-) with cell dimensions a = 9.06(2), b = 9.80(2), c = 8.78(2) Å, α = 110.6(5), β = 95.1(5), and γ = 92.0(5)°. The measured and calculated values for the density (for Z = 2) are 2.02 and 2.00 g/cm3, respectively. A total of 1568 non-zero reflexions has been obtained by photographic methods. The structure was solved by Patterson methods and refined by the full-matrix least square method to a conventional R factor of 0.097. The crystal structure shows that the molecule is a dimer, and that the coordination around the metal atom is intermediate between square pyramidal and trigonal bipyramidal, although somewhat closer to the former. One sulphur atom from a thiourea molecule coordinates to two adjacent cadmium atoms at distances 2.627(7) and 2.870(7). The other three bond lengths in the coordination polyhedra are: CdS(2) = 2.538(6), CdS(3) = 2.627(6) (both S from thiourea molecules) and CdO(1) = 2.339(15) (the O belonging to the sulphate group)." @default.
- W2045011775 created "2016-06-24" @default.
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- W2045011775 date "1969-01-01" @default.
- W2045011775 modified "2023-09-23" @default.
- W2045011775 title "The crystal structure of a five-coordinated cadmium(II) complex: Tristhiourea-cadmium sulphate" @default.
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- W2045011775 doi "https://doi.org/10.1016/s0020-1693(00)92562-3" @default.
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