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- W2045013957 abstract "Abstract The IR spectroscopy has been used to study models of polyurethanes containing different hard segments. The spectra of toluene-2,6-bis(methyl) and 4,4′-diphenylmethane-bis(methyl) carbamates at different temperatures were studied. The absorption curves of the free and associated carbamate molecules were compared with experimental IR spectra. The characteristic features of toluene-2,6-bis(methyl) carbamate and methyl-N-methyl carbamate clusters were revealed. The IR spectra for the two most stable toluene-2,6-bis(methyl) carbamate conformations were compared. The origin of the multiplet structure of bands in the experimental IR spectra of polyurethanes was discussed. The results obtained can be used for the analysis of the chemical and physical transformations in urethanes and polyurethanes." @default.
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- W2045013957 date "2000-03-01" @default.
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- W2045013957 title "The IR spectra and hydrogen bonding of toluene-2,6-bis(methyl) and 4,4′-diphenylmethane-bis(methyl) carbamates" @default.
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- W2045013957 doi "https://doi.org/10.1016/s0022-2860(99)00321-x" @default.
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