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• W2045014505 abstract "The exchange kinetics of Gd(DTPA-BMEA) with the radioactive tracer Eu(III) have been studied in aqueous solution of 0.15 M ionic strength and 25°C. The exchange is a first-order reaction with the rate expression containing both acid-dependent and acid-independent terms. At pH>6, the exchange is governed by direct reaction of Eu(III) ions with Gd(DTPA-BMEA), while below pH 6, the rate determining step is proton-catalyzed dissociation of the complex with a first-order dependence on [H+]. The relatively slow association and dissociation of the Ln(DTPA-BMEA) complexes can be attributed to steric effects related to the binding of the two methoxyethylamide groups." @default.
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• W2045014505 date "1997-10-01" @default.
• W2045014505 modified "2023-09-26" @default.
• W2045014505 title "The kinetics of exchange between a lanthanide ion and the gadolinium complex of N,N″-bis(2-methoxyethylamide-carbamoylmethyl)-diethylenetriamine-N,N′,N″-triacetate" @default.
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• W2045014505 doi "https://doi.org/10.1016/s0020-1693(97)05513-8" @default.
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