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• W2045108022 endingPage "777" @default.
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• W2045108022 abstract "Abstract The gas‐phase kinetics of CHBr 2 + NO 2 and CH 3 CHBr + NO 2 reactions have been studied in direct time resolved measurements using a tubular flow reactor coupled to a photoionization mass spectrometer. The radicals were generated by pulsed laser photolysis of bromoform and 1,1‐dibromoethane at 248 nm. The subsequent decays of the radical concentrations were monitored as a function of [NO 2 ] under pseudo–first‐order conditions. The rate coefficients of both reactions are independent of bath gas (He) pressure and display negative temperature dependence under the conditions of 2–6 Torr pressure (He) and 250–480 K. The obtained bimolecular rate coefficients are k (CHBr 2 + NO 2 ) = (9.8 ± 0.4) × 10 −12 ( T /300 K) −1.65 ± 0.18 cm 3 s −1 (288–483 K) and k (CH 3 CHBr + NO 2 ) = (2.27 ± 0.06) × 10 −11 ( T /300 K) −1.28 ± 0.11 cm 3 s −1 (250–483 K), with the uncertainties given as one standard error. Estimated overall uncertainties in the measured bimolecular reaction rate coefficients are ±25%. The reaction products identified were CBr 2 O for the CHBr 2 + NO 2 reaction and CHBrO and CH 3 CHO with minor amounts of CH 3 for the CH 3 CHBr + NO 2 reaction, respectively. © 2012 Wiley Periodicals, Inc. Int J Chem Kinet 44: 767–777, 2012" @default.
• W2045108022 created "2016-06-24" @default.
• W2045108022 creator A5029167153 @default.
• W2045108022 creator A5052286969 @default.
• W2045108022 creator A5073788174 @default.
• W2045108022 date "2012-04-29" @default.
• W2045108022 modified "2023-10-17" @default.
• W2045108022 title "Kinetics of the brominated alkyl radical (CHBr₂ , CH₃ CHBr) reactions with NO₂ in the temperature range 250-480 K" @default.
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• W2045108022 doi "https://doi.org/10.1002/kin.20725" @default.
• W2045108022 hasPublicationYear "2012" @default.
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