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- W2045119727 abstract "CuOHCI and the three polymorphs of Cu2(OH)3Cl (botallackite, atacamite, and paratacamite) have been studied by means of thermogravimetry, differential scanning calorimetry, infrared spectroscopy, and X-ray powder diffraction. The OH stretching frequencies show a progressive increase in the strength of hydrogen-bonding in the order botallackite < atacamite < paratacamite. This correlates with the order of thermal stabilites, as evidenced by the decomposition temperatures and peak areas in the thermograms. Each of the copper hydroxychlorides passes through an intermediate phase having the stoichiometry Cu2OCl2 before being completely converted to CuO. Sealed tube experiments show that botallackite and atacamite are readily thermally converted to paratacamite, but that the latter can be kept at 500°C for hours without any detectable effects if the products of reaction, viz., H2O and Cl2 are not permitted to escape. The relative enthalpies of the thermal decomposition reactions of the hydroxychlorides and the intermediate Cu2OCl2 can be deduced from the DSC curves." @default.
- W2045119727 created "2016-06-24" @default.
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- W2045119727 date "1972-01-01" @default.
- W2045119727 modified "2023-09-27" @default.
- W2045119727 title "Thermochemical properties of the copper(ii) hydroxychlorides" @default.
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- W2045119727 doi "https://doi.org/10.1016/0040-6031(72)85029-9" @default.
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