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- W2045121013 abstract "Aryldiazo substituents were used in nucleophilic aromatic substitution reactions of halogens. The Ph-N=N- group activates ortho fluorine atoms toward alkylthiolation under mild conditions. In contrast, the Me(2)N-C(6)H(4)-N=N- group has virtually no activation effect in nucleophilic aromatic substitution, and serves as a neutral mask for the amino group. The Ph-N=N- group was efficiently introduced by diazo coupling of aryllithium with dry PhN(2)(+)BF(4)(-) salt." @default.
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- W2045121013 date "2004-02-13" @default.
- W2045121013 modified "2023-09-27" @default.
- W2045121013 title "Azo Group-Assisted Nucleophilic Aromatic Substitutions in Haloarene Derivatives: Preparation of Substituted 1-Iodo-2,6-bispropylthiobenzenes" @default.
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- W2045121013 doi "https://doi.org/10.1021/jo0302399" @default.
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