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- W2045167623 abstract "In the title compound three bidentate 2-pyridine-thiolato ligands (2-SPy) together with p-tolyl form a distorted pentagonal bipyramid around Sn. Two S atoms and three N atoms form the pentagonal plane. One S and the C(p-tolyl) atom are in the axial positions. The distortion of the molecule is explicated by the axial S-Sn-C angle of 156.0 (3) o and by the distance of 0.635 (7) A of one of the N atoms from the pentagonal plane. The Sn-S distances in the plane are longer [2.571 (3) A] than the axial Sn-S bond [2.486 (3) A]. The Sn-N distances are in the range 2.468 (8)±0.024 A. Intermolecular distances shorter than the sum of the van der Waals radii do not exist" @default.
- W2045167623 created "2016-06-24" @default.
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- W2045167623 date "1994-02-15" @default.
- W2045167623 modified "2023-09-25" @default.
- W2045167623 title "Tris(2-pyridinethiolato)(p-tolyl)tin(IV), [Sn(C5H4NS)3(C7H7)]" @default.
- W2045167623 doi "https://doi.org/10.1107/s0108270193007310" @default.
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