FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2045169964> ?p ?o ?g. }

• W2045169964 endingPage "60" @default.
• W2045169964 startingPage "46" @default.
• W2045169964 abstract "The available experimental energy levels of Nd3+ ions doped into single crystals of BaY2F8, LiKYF5, and K2YF5, which exhibit low site symmetry, are reanalyzed. A combined approach based on the ascent/descent in symmetry (ADS) method, the superposition model (SPM) analysis, and the pseudosymmetry axes method (PAM) is utilized to extract the crystal field (CF) parameters, Bkq, from experimental spectra. Corresponding sets of the free-ion parameters are also fitted. The crystallographic data are used to establish the axis systems most appropriate for approximation of the actual monoclinic C2 site symmetry to higher orthorhombic D2 and tetragonal D4 symmetry used in CF calculations for BaY2F8. Similarly, for triclinic C1 site symmetry in LiKYF5 and K2YF5 approximation to monoclinic C2 and orthorhombic D2 symmetry for LiKYF5, whereas the monoclinic Cs symmetry for K2YF5, are considered. It is shown that the C2v approximation used previously for K2YF5:Nd3+ is not suitable. SPM enables to calculate for the unapproximated and idealized polyhedrons YF8 in a given ion–host system of the combined coordination factors Sgk,q expressed in the modified crystallographic axis system CAS* and approximated symmetry adapted axis systems, respectively. The quantities Sgk,q serve as input for PAM calculations for independent determination of the axis system appropriate for higher symmetry approximations. The pseudosymmetry axes represent the axis system that reflects most closely the approximated higher symmetry of the nearest ligands in a paramagnetic complex embodied in the 4th-rank CF parameters. The combined ADS/SPM/PAM approach provides sets of starting CF parameters (CFPs) in well-defined axis systems. Multiple fittings starting from different points in the CF parameter space yield converging solutions, thus increasing the reliability of the final optimized solutions, which may be then considered as the global minima. The present CF analysis, unlike the previous ones, takes into account the low symmetry aspects inherent in the CF Hamiltonian and optical spectra. The improved and more reliable sets of CFPs are generated as well as modified assignments of the CF energy levels are proposed for BaY2F8:Nd3+. The present considerations enable also clarification of some ambiguous points occurring in previous studies." @default.
• W2045169964 created "2016-06-24" @default.
• W2045169964 creator A5032558717 @default.
• W2045169964 creator A5067753240 @default.
• W2045169964 creator A5076452276 @default.
• W2045169964 date "2012-02-01" @default.
• W2045169964 modified "2023-10-06" @default.
• W2045169964 title "Energy levels and crystal field parameters for Nd3+ ions in BaY2F8, LiKYF5, and K2YF5 single crystals" @default.
• W2045169964 cites W1649821324 @default.
• W2045169964 cites W1964084501 @default.
• W2045169964 cites W1970146484 @default.
• W2045169964 cites W1978496950 @default.
• W2045169964 cites W1996101925 @default.
• W2045169964 cites W1996309741 @default.
• W2045169964 cites W2012231272 @default.
• W2045169964 cites W2014030748 @default.
• W2045169964 cites W2016328492 @default.
• W2045169964 cites W2034111652 @default.
• W2045169964 cites W2036178278 @default.
• W2045169964 cites W2039083972 @default.
• W2045169964 cites W2039877565 @default.
• W2045169964 cites W2042456185 @default.
• W2045169964 cites W2045348704 @default.
• W2045169964 cites W2056268011 @default.
• W2045169964 cites W2062392389 @default.
• W2045169964 cites W2066109513 @default.
• W2045169964 cites W2068150705 @default.
• W2045169964 cites W2068389056 @default.
• W2045169964 cites W2070992190 @default.
• W2045169964 cites W2088091357 @default.
• W2045169964 cites W2090452240 @default.
• W2045169964 cites W2166583754 @default.
• W2045169964 cites W2952475006 @default.
• W2045169964 cites W3198245712 @default.
• W2045169964 cites W4234686240 @default.
• W2045169964 cites W4234850558 @default.
• W2045169964 doi "https://doi.org/10.1016/j.saa.2011.11.008" @default.
• W2045169964 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22177223" @default.
• W2045169964 hasPublicationYear "2012" @default.
• W2045169964 type Work @default.
• W2045169964 sameAs 2045169964 @default.
• W2045169964 citedByCount "21" @default.
• W2045169964 countsByYear W20451699642012 @default.
• W2045169964 countsByYear W20451699642013 @default.
• W2045169964 countsByYear W20451699642014 @default.
• W2045169964 countsByYear W20451699642015 @default.
• W2045169964 countsByYear W20451699642016 @default.
• W2045169964 countsByYear W20451699642018 @default.
• W2045169964 countsByYear W20451699642019 @default.
• W2045169964 countsByYear W20451699642020 @default.
• W2045169964 countsByYear W20451699642021 @default.
• W2045169964 countsByYear W20451699642023 @default.
• W2045169964 crossrefType "journal-article" @default.
• W2045169964 hasAuthorship W2045169964A5032558717 @default.
• W2045169964 hasAuthorship W2045169964A5067753240 @default.
• W2045169964 hasAuthorship W2045169964A5076452276 @default.
• W2045169964 hasConcept C115624301 @default.
• W2045169964 hasConcept C121332964 @default.
• W2045169964 hasConcept C145148216 @default.
• W2045169964 hasConcept C170751736 @default.
• W2045169964 hasConcept C185592680 @default.
• W2045169964 hasConcept C199360897 @default.
• W2045169964 hasConcept C2524010 @default.
• W2045169964 hasConcept C2779886137 @default.
• W2045169964 hasConcept C2781285689 @default.
• W2045169964 hasConcept C33923547 @default.
• W2045169964 hasConcept C37243968 @default.
• W2045169964 hasConcept C41008148 @default.
• W2045169964 hasConcept C41999313 @default.
• W2045169964 hasConcept C42228675 @default.
• W2045169964 hasConcept C61276311 @default.
• W2045169964 hasConcept C62520636 @default.
• W2045169964 hasConcept C8010536 @default.
• W2045169964 hasConceptScore W2045169964C115624301 @default.
• W2045169964 hasConceptScore W2045169964C121332964 @default.
• W2045169964 hasConceptScore W2045169964C145148216 @default.
• W2045169964 hasConceptScore W2045169964C170751736 @default.
• W2045169964 hasConceptScore W2045169964C185592680 @default.
• W2045169964 hasConceptScore W2045169964C199360897 @default.
• W2045169964 hasConceptScore W2045169964C2524010 @default.
• W2045169964 hasConceptScore W2045169964C2779886137 @default.
• W2045169964 hasConceptScore W2045169964C2781285689 @default.
• W2045169964 hasConceptScore W2045169964C33923547 @default.
• W2045169964 hasConceptScore W2045169964C37243968 @default.
• W2045169964 hasConceptScore W2045169964C41008148 @default.
• W2045169964 hasConceptScore W2045169964C41999313 @default.
• W2045169964 hasConceptScore W2045169964C42228675 @default.
• W2045169964 hasConceptScore W2045169964C61276311 @default.
• W2045169964 hasConceptScore W2045169964C62520636 @default.
• W2045169964 hasConceptScore W2045169964C8010536 @default.
• W2045169964 hasLocation W20451699641 @default.
• W2045169964 hasLocation W20451699642 @default.
• W2045169964 hasOpenAccess W2045169964 @default.
• W2045169964 hasPrimaryLocation W20451699641 @default.
• W2045169964 hasRelatedWork W15903973 @default.
• W2045169964 hasRelatedWork W1967558677 @default.
• W2045169964 hasRelatedWork W2050815233 @default.
• W2045169964 hasRelatedWork W2058650698 @default.

• next