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• W2045172802 endingPage "5824" @default.
• W2045172802 startingPage "5809" @default.
• W2045172802 abstract "Modification of hydrogen-terminated Si(1 1 1) surfaces by hydrosilylation of activated alkenes and further chemical transformation of the modified surfaces is reported. A Si(1 1 1)–H surface was reacted with activated alkenes such as acrylate esters, acrylonitrile, and maleic anhydride under mild conditions to give modified surfaces with terminal functional groups. A modified surface with a terminal ester group was reduced by LiAlH4 to give a hydroxy-terminated surface, and the hydroxy-terminated surface was transformed to a bromo-terminated surface. XPS analysis revealed that the brominated surface (Si(1 1 1)–CH2CH2CH2Br) had 32% coverage with the 3-bromopropyl group. Ester and amide formation reactions were carried out on hydroxy- and carboxy-terminated Si surfaces by reaction with tert-butoxycarbonyl glycine, glycine tert-butyl ester, 2,2,2-trifluoroethanol and 4-trifluoromethylbenzyl alcohol in the presence of carbodiimide. XPS characterization indicated that the esters and amide were successfully formed with coverage ranging from 16% to 58%. Coverage ratios of octadecyl ester modified surfaces were also estimated by combination of surface reduction and gas chromatography analysis to be 25–35%." @default.
• W2045172802 created "2016-06-24" @default.
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• W2045172802 date "2006-12-01" @default.
• W2045172802 modified "2023-09-23" @default.
• W2045172802 title "Modification and chemical transformation of Si(111) surface" @default.
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• W2045172802 doi "https://doi.org/10.1016/j.jorganchem.2006.09.048" @default.
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