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• W2045174765 abstract "A study of point defects and nonstoichiometry in GaAs is presented. Standard methods of chemical thermodynamics are used to derive expressions for the equilibrium concentrations, as a function of temperature and arsenic pressure, of the following defects; arsenic monovacancies, gallium monovacancies, gallium divacancies and appropriately charged versions of these three. This choice of defects is made on the strength of the evidence of the published experimental results relating directly to point defects in GaAs. Values for the required equilibrium constants are obtained by a combination of a priori estimates and matching with this experimental data at certain points. Consistent agreement with the experimental data is obtained, indicating for example that defect concentration in the region 1018–1019 cm−3 in melt grown material are not unreasonable. The set of equilibrium constants on which the calculations are based must, however, be regarded as provisional until more extensive data is available for comparison. Using these equilibrium constants the minimum practical deviation from stoichiometry and the width of the existence region of solid GaAs are calculated as a function of temperature." @default.
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• W2045174765 date "1971-01-01" @default.
• W2045174765 modified "2023-10-18" @default.
• W2045174765 title "Calculations of point defect concentrations and nonstoichiometry in GaAs" @default.
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• W2045174765 doi "https://doi.org/10.1016/s0022-3697(71)80140-3" @default.
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