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- W2045177773 abstract "Tetranuclear complexes with chain-like arrangements of metal atoms and bridging arsenic atoms were obtained by a two-step procedure. The first step involved opening of the metalmetal bonds in dinuclear complexes by norbornadiene, in the second step the norbornadiene was replaced by two molecules of an organometallic Lewis base of the kind LnMAsMe2. The starting complexes contained FeCo and MnCo bonds, the organometallic Lewis bases were of the FeAs, CrAs, and MoAs type. The structure of the new complexes were deduced from spectroscopic data and in one case proved by a crystal structure analysis. Tetranuclear complexes with chain-like arrangements of metal atoms and bridging arsenic atoms were obtained by a two-step procedure. The first step involved opening of the metalmetal bonds in dinuclear complexes by norbornadiene, in the second step the norbornadiene was replaced by two molecules of an organometallic Lewis base of the kind LnMAsMe2. The starting complexes contained FeCo and MnCo bonds, the organometallic Lewis bases were of the FeAs, CrAs, and MoAs type. The structure of the new complexes were deduced from spectroscopic data and in one case proved by a crystal structure analysis." @default.
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- W2045177773 date "1980-05-01" @default.
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- W2045177773 title "Reaktivität von metall—metall-bindungen. Vierkernkomplexe mit kettenförmiger anordnung von metall- und brükenatomen" @default.
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- W2045177773 doi "https://doi.org/10.1016/s0022-328x(00)88558-7" @default.
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