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- W2045179082 abstract "A new UHV technique is presented for evaluating the adsorption–desorption properties of UHV vapor-deposited metal particles supported on insulating substrates. Desorption studies of CO from particulate and continuous Pd films supported on mica were performed. The desorption results indicate that (1) the CO desorption energies from the deposited metals are much lower than those from bulk single crystals. (2) two desorption states were found for the vapor-deposited films, and (3) the lower energy desorption peak of the vapor-deposited films is coverage dependent with an activation energy of 27.25–2.85σ kcal/mol. Possible reasons for the difference between previously reported CO desorption studies on bulk substrates and the present results are discussed." @default.
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- W2045179082 date "1978-03-01" @default.
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- W2045179082 title "Chemisorption of CO on Pd particles supported on mica" @default.
- W2045179082 doi "https://doi.org/10.1116/1.569474" @default.
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