Matches in SemOpenAlex for { <https://semopenalex.org/work/W2045180535> ?p ?o ?g. }
Showing items 1 to 70 of
70
with 100 items per page.
- W2045180535 abstract "Photochemical reaction of N-bromobis(trifluoromethyl)amine with 1-fluoropropene in the vapour phase gives a mixture of the 1 : 1 adducts 2-bromo-1-fluoro-NN-bis(trifluoromethyl)propylamine and 2-bromo-2-fluoro-1-methyl-NN-bis(trifluoromethyl)ethylamine in the ratio 46 : 54. Under conditions conducive to the formation of ionic intermediates (–78 °C in the dark in the liquid phase), stereospecific anti-addition to the olefin takes place and the 1 : 1 adducts are formed in the ratio 90 : 10 (cis-isomer) and 77 : 23 (trans-isomer). All the adducts undergo dehydrobromination by anti-elimination to give the corresponding (E)- or (Z)-olefins, except for (1R,2S)-2-bromo-1-fluoro-NN-bis(trifluoromethyl)propylamine, which undergoes mainly syn-elimination to afford a mixture of (E)- and (Z)-1-fluoro-NN-bis(trifluoromethyl)prop-1-enylamine in the ratio 82 : 18." @default.
- W2045180535 created "2016-06-24" @default.
- W2045180535 creator A5024659579 @default.
- W2045180535 creator A5050277317 @default.
- W2045180535 creator A5057500075 @default.
- W2045180535 date "1976-01-01" @default.
- W2045180535 modified "2023-09-26" @default.
- W2045180535 title "Polyfluoroalkyl derivatives of nitrogen. Part XLIII. Reactions of N-bromobis(trifluoromethyl)amine with 1-fluoropropene under free-radical and under ionic conditions" @default.
- W2045180535 doi "https://doi.org/10.1039/p19760000556" @default.
- W2045180535 hasPublicationYear "1976" @default.
- W2045180535 type Work @default.
- W2045180535 sameAs 2045180535 @default.
- W2045180535 citedByCount "3" @default.
- W2045180535 crossrefType "journal-article" @default.
- W2045180535 hasAuthorship W2045180535A5024659579 @default.
- W2045180535 hasAuthorship W2045180535A5050277317 @default.
- W2045180535 hasAuthorship W2045180535A5057500075 @default.
- W2045180535 hasConcept C108204754 @default.
- W2045180535 hasConcept C131779359 @default.
- W2045180535 hasConcept C155647269 @default.
- W2045180535 hasConcept C161790260 @default.
- W2045180535 hasConcept C178790620 @default.
- W2045180535 hasConcept C185592680 @default.
- W2045180535 hasConcept C187921627 @default.
- W2045180535 hasConcept C2776442012 @default.
- W2045180535 hasConcept C2778678469 @default.
- W2045180535 hasConcept C2780263894 @default.
- W2045180535 hasConcept C2780850051 @default.
- W2045180535 hasConcept C51886252 @default.
- W2045180535 hasConcept C5304478 @default.
- W2045180535 hasConceptScore W2045180535C108204754 @default.
- W2045180535 hasConceptScore W2045180535C131779359 @default.
- W2045180535 hasConceptScore W2045180535C155647269 @default.
- W2045180535 hasConceptScore W2045180535C161790260 @default.
- W2045180535 hasConceptScore W2045180535C178790620 @default.
- W2045180535 hasConceptScore W2045180535C185592680 @default.
- W2045180535 hasConceptScore W2045180535C187921627 @default.
- W2045180535 hasConceptScore W2045180535C2776442012 @default.
- W2045180535 hasConceptScore W2045180535C2778678469 @default.
- W2045180535 hasConceptScore W2045180535C2780263894 @default.
- W2045180535 hasConceptScore W2045180535C2780850051 @default.
- W2045180535 hasConceptScore W2045180535C51886252 @default.
- W2045180535 hasConceptScore W2045180535C5304478 @default.
- W2045180535 hasLocation W20451805351 @default.
- W2045180535 hasOpenAccess W2045180535 @default.
- W2045180535 hasPrimaryLocation W20451805351 @default.
- W2045180535 hasRelatedWork W1549737234 @default.
- W2045180535 hasRelatedWork W1978998527 @default.
- W2045180535 hasRelatedWork W1979672153 @default.
- W2045180535 hasRelatedWork W2040329223 @default.
- W2045180535 hasRelatedWork W2043623083 @default.
- W2045180535 hasRelatedWork W2055268775 @default.
- W2045180535 hasRelatedWork W2060306317 @default.
- W2045180535 hasRelatedWork W2066051438 @default.
- W2045180535 hasRelatedWork W2081394844 @default.
- W2045180535 hasRelatedWork W2127460670 @default.
- W2045180535 hasRelatedWork W2127927724 @default.
- W2045180535 hasRelatedWork W2148578671 @default.
- W2045180535 hasRelatedWork W2949157342 @default.
- W2045180535 hasRelatedWork W2950358311 @default.
- W2045180535 hasRelatedWork W2951102474 @default.
- W2045180535 hasRelatedWork W2952170097 @default.
- W2045180535 hasRelatedWork W2953102047 @default.
- W2045180535 hasRelatedWork W2819459013 @default.
- W2045180535 hasRelatedWork W2836165752 @default.
- W2045180535 hasRelatedWork W2860338168 @default.
- W2045180535 isParatext "false" @default.
- W2045180535 isRetracted "false" @default.
- W2045180535 magId "2045180535" @default.
- W2045180535 workType "article" @default.