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- W2045184009 abstract "Abstract Two novel orotate complexes, mononuclear [Ni(HOr)(H2O)2(etpy)]·H2O (1) and dinuclear [Cu(μ-HOr)(etpy)]2 (2) (etpy = 2-hydroxyethylpyridine, HOr2− = dianionic orotate), have been prepared and characterized by elemental analyses, spectroscopic (IR, UV–vis), thermal, magnetic and single crystal X-ray diffraction studies. The mononuclear Ni(II) complex crystallizes in the triclinic space group P 1 ¯ and the dinuclear copper(II) complex crystallizes in the monoclinic space group P21/c. The mononuclear complex consists of individual units in which nickel(II) lies on the inversion center and has octahedral coordination by bidentate HOr2−, bidentate etpy and two aqua ligands. The dinuclear copper(II) complex composed of a double-orotate bridge and bidentate etpy ligands. Each HOr2− ligand simultaneously exhibits chelating bidentate and bridging coordination modes. HOr2− is tricoordinated to one copper atom through N3 atom of pyrimidine ring, one oxygen atom of the carboxylate group as a bidentate ligand and to the other copper ion via the other oxygen of the carboxylate group. The structural units are joined into the framework by the hydrogen bonds in 1 and 2." @default.
- W2045184009 created "2016-06-24" @default.
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- W2045184009 date "2008-10-01" @default.
- W2045184009 modified "2023-09-22" @default.
- W2045184009 title "The first dinuclear orotate complex: Syntheses, spectral, thermal and structural characterization of supramolecular orotate complexes of nickel(II) and copper(II) with 2-hydroxyethylpyridine" @default.
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- W2045184009 doi "https://doi.org/10.1016/j.molstruc.2008.02.029" @default.
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