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- W2045184989 abstract "The crystal structure of LiBiPd2O4 has been determined from X-ray powder diffraction data. This compound is tetragonal [space group P4nmm (No. 129) (Z = 2)] with a = 6.9109(2) Å, c = 4.3557(2) Å. The structure was solved ab initio from the X-ray powder data by direct methods and refined by the Rietveld profile technique. LiBiPd2O4 exhibits a completely new three-dimensional structure type with Li+, Bi3+, and Pd2+ in tetrahedral, square pyramidal, and square planar coordinations, respectively. Oxygen atoms draw a [4.82] plane net. The role of the lone pair is investigated and the subnetwork of Pd square planes is compared to corresponding ones in other structures." @default.
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- W2045184989 date "1989-07-01" @default.
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- W2045184989 title "Complex palladium oxides. V. Crystal structure of LiBiPd2O4: An example of three different fourfold coordinations of cations" @default.
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- W2045184989 doi "https://doi.org/10.1016/0022-4596(89)90201-6" @default.
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