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- W2045188145 abstract "Low-frequency Raman and differential scanning calorimetry (DSC) investigations were carried out during a structural transformation of supercooled liquid salol (phenyl salicylate) in a wide temperature range. DSC experiments indicate that in the supercooled liquid salol at temperature ∼ 40 K above the glass transition temperature metastable nuclei start to form. During subsequent cooling the nuclei become an important element of the glass structure, and thereby are considered as a measure of the intermediate range order in this glass. It was shown that the crystalline structure of the metastable nuclei differ from that of the stable nuclei. Low-frequency Raman spectra of the glassy salol show a broad band in the spectral range from 14.5 to 17.2 cm − 1; the so called 'Boson peak', which can be interpreted in terms of its relationship to the formation of structured clusters, with typical sizes in the nanometer range (critical radii)." @default.
- W2045188145 created "2016-06-24" @default.
- W2045188145 creator A5011022337 @default.
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- W2045188145 date "2010-03-23" @default.
- W2045188145 modified "2023-09-24" @default.
- W2045188145 title "The role of nucleation in vitrification of supercooled liquids" @default.
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- W2045188145 doi "https://doi.org/10.1088/0953-8984/22/15/155108" @default.
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