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- W2045202973 abstract "Concentrated aqueous solutions of a nonionic surfactant, C12H25(OCH2CH2)21OH (21ED), were studied using a spin probe method. The correlation time (τc) of the probe, 2,4-dinitrophenyl-hydrazone of 2,2,6,6-tetramethyl-4-piperidone N-oxide, in the micelle was ∼1.2 × 10−9 sec, suggesting that the probe was in the polyoxyethylene group. The value did not change greatly in the region of 25–90% water content, in contrast to the macroscopic properties. The hydration of the group of the surfactant in the micelle was discussed on the basis of τc, the hyperfine coupling constant, and the γmax of UV absorption. It was concluded that the polyoxyethylene group was hydrated by the ratio of about one H2O molecule per oxygen atom of the ether linkage." @default.
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- W2045202973 date "1978-02-01" @default.
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- W2045202973 title "Spin probe study of concentrated aqueous solutions of nonionic surfactant" @default.
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