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- W2045209831 abstract "The intrinsic viscosities of a series of dendritic, hyperbranched, branched and linear polymers were predicted using a bead model. The model is an extension of the Muthukumar model allowing for a large range of degrees of branching. Intrinsic visosities were calculated from the radius of gyration and by using the hydrodynamic tensor approach. It is found that (flexible) hyperbranched polymers exhibit a maximum of intrinsic viscosity as function of molecular weight, as dendrimers do, but the maximum is situated at a higher level of intrinsic viscosity and shifted to higher molecular weights. Terminating the end groups with long-chain aliphatic tails decreases the intrinsic viscosity once as a certain threshold molecular weight is exceeded. The value of the latter increases with increasing degree of branching." @default.
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- W2045209831 date "1998-01-01" @default.
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- W2045209831 title "Prediction of intrinsic viscosities of dendritic, hyperbranched and branched polymers" @default.
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- W2045209831 doi "https://doi.org/10.1016/s1089-3156(98)00013-0" @default.
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