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- W2045226502 abstract "Taylor dispersion has gained widespread popularity for measuring diffusion in liquids. The usual procedure is to inject small volumes of solution containing solute at concentration c + Δc into carrier streams of composition c. Binary mutual diffusion coefficients D are evaluated from the Gaussian distribution of the dispersed solute measured at the outlet of a long capillary tube. As a result of strong dilution of the injected solute with the carrier solution, obtaining favorable signal-to-noise ratios for the measured profiles can require unacceptably large Δc values for solutions with strongly composition-dependent diffusion coefficients or broad dispersion profiles produced by slowly diffusing solutes. For these systems, D can be reliably evaluated from error-function profiles generated by changing the solution flowing into dispersion tube from composition c − (Δc/2) to c + (Δc/2). There are no dilution factors, so Δc can be orders of magnitude smaller than the values employed in conventional pulse..." @default.
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- W2045226502 date "2007-03-01" @default.
- W2045226502 modified "2023-09-24" @default.
- W2045226502 title "Ternary Mutual Diffusion Coefficients from Error-Function Dispersion Profiles: Aqueous Solutions of Triton X-100 Micelles + Poly(ethylene glycol)" @default.
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- W2045226502 doi "https://doi.org/10.1021/je0603731" @default.
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