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- W2045231405 abstract "Abstract The novel cationic complex [Ag 14 (C 2 t Bu) 12 ] 2+ has been synthesized by four reactions: reaction of [Ag(C 2 t Bu)] n and AgBF 4 in acetone in a 6:1 mole ratio, that of HC≡C t Bu and AgBF 4 in water in the absence of a base, treatment of [AgC 2 t Bu] n with HBF 4 in acetone or that of {[Ag 3 (C 2 t Bu) 2 ][BF 4 ]} n with [Ag(C 2 t Bu)] n in a 1:4 mole ratio. Single‐crystal X‐ray studies showed it to be a hexacapped cube of silver( I ) atoms, with twelve η 1 , μ 3 ‐C 2 t Bu ligands. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
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- W2045231405 date "2006-05-24" @default.
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- W2045231405 title "Synthesis and Structural Characterization of a Halide‐Free Rhombohedral Silver‐Alkynyl Cage Complex [Ag<sub>14</sub>(C<sub>2</sub><i>t</i>Bu)<sub>12</sub>][BF<sub>4</sub>]<sub>2</sub>" @default.
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- W2045231405 doi "https://doi.org/10.1002/ejic.200600128" @default.
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