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- W2045246564 abstract "Abstract Infrared-infrared double-resonance spectra have been recorded for samples of methyl fluoride gas in an excess of hydrogen, helium, argon, and xenon, as well as for mixtures of 12 CH 3 F and 13 CH 3 F. The double-resonance effects appear as a narrow transferred spike superimposed on a broad Gaussian lineshape of the expected Doppler width. When the foreign gas has a dipole moment or is a relatively light perturber, the spike dominates the lineshape, but when the foreign gas is a relatively heavy atom, the Gaussian dominates. The spectra for all of the samples show evidence of a Δ k = 3 n ( n = an integer or zero) selection rule for collisionally induced rotational transitions. The spectra with argon and xenon as foreign gas demonstrate that collisions with these atoms can induce direct vibration-rotation energy changes from v 3 = 1 to v 6 = 1 in methyl fluoride and that the selection rule for these transitions is Δ( k − l ) = 3 n . The double-resonance spectra with argon and xenon as a foreign gas also show a frequency shift that is substantially larger than the shift for single-resonance spectra in the same mixture. One-dimensional collision kernels have been calculated by classical mechanics and appear to display most of the characteristics of the experimental spectra." @default.
- W2045246564 created "2016-06-24" @default.
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- W2045246564 date "1992-05-01" @default.
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- W2045246564 title "Infrared-infrared double resonance of methyl fluoride in foreign gases" @default.
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- W2045246564 doi "https://doi.org/10.1016/0022-2852(92)90484-6" @default.
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