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• W2045247813 abstract "Calcium titanate (CaTiO3), α-tricalcium phosphate (α-TCP) and hydroxyapatite (HAp) films were prepared by metal-organic chemical vapor deposition (MOCVD) using Ca(dpm)2, Ti(O-i-Pr)2(dpm)2 and (C6H5O)3PO precursors. The phases, composition and surface morphology of these films changed depending on substrate temperature (Tsub), total pressure (Ptot) and molar ratio of each precursors (RCa/Ti, RCa/P). The surface morphology of CaTiO3 films changed from granular structure to cauliflower-like texture, and its cross-sectional morphology changed from dense to columnar structure with increasing Tsub. α-TCP and HAp films had granular surface and dense cross-sectional morphology. CaTiO3, α-TCP and HAp films were immersed in a Hanks' solution for 28 d. Apatite formation rate strongly depended on the surface morphology of CaTiO3 film, and apatite covered CaTiO3 film having a granular surface after 4 w while CaTiO3 film having a cauliflower-like texture after 3 d. Apatite covered α-TCP films after 14 d and HAp films after 6 h, respectively. HAp films prepared by MOCVD were promising as bone conductive materials." @default.
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• W2045247813 date "2009-01-01" @default.
• W2045247813 modified "2023-10-16" @default.
• W2045247813 title "Apatite formation behavior on bio-ceramic films prepared by MOCVD" @default.
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• W2045247813 doi "https://doi.org/10.2109/jcersj2.117.461" @default.
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