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• W2045251188 abstract "Metal Complexes of Functionalized Sulfur‐Containing Ligands, III [1] . – Reactions of (Ph 3 P) 2 Pt(η 2 ‐C 2 H 4 ) with Acyclic and Cyclic Thiosulfinates: Platinum(II)‐thiolato Complexes with Sulfenato Ligands. Crystal Structure Determination of (4‐Sulfido‐1‐butanesulfenato‐ S,S′ )bis(triphenylphosphane)platinum(II) magnified image Oxidative addition of acyclic thiosulfinates R′–S(O)–S–R ( 1a : R′ = R = CH 3 ; 1b : R′ = R = Ph; 1c : R′ = R = p ‐CH 3 C 6 H 4 ; 1d : R′ = p ‐ClC 6 H 4 , R = C 6 H 5 ) to (Ph 3 P) 2 Pt(η 2 ‐C 2 H 4 ) ( 4 ) leads to the monomeric trans ‐configurated complexes (Ph 3 P) 2 Pt[S(O)R′](SR) ( 5a–d ) which loose one PPh 3 ligand in solution and form the dimetallic thiolato‐bridged compounds [(Ph 3 P)Pt[S(O)R′](μ‐SR)] 2 . The cyclic thiosulfinates 1,2‐dithiane S‐oxide ( 2 ) and 1,4‐dihydro‐2,3‐benzodithiine S‐oxide ( 3 ) react with 4 to yield the monomeric seven‐membered chelate magnified image ( 7 ) and the dimetallic complex [(Ph 3 P)Pt–S(O)–CH 2 –C 6 H 4 –CH 2 –μ‐S] 2 ( 8 ), respectively. In 7 , characterized by X‐ray diffraction, a tetrahedral distortion of the square planar coordination of the platinum(II) atoms is remarkable; the planes Pt,P(1),P(2) and Pt,S(1),S(2) form an angle of 16.1°." @default.
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• W2045251188 date "1992-05-01" @default.
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• W2045251188 title "Metallkomplexe mit funktionalisierten Schwefel‐Liganden, III. Reaktionen von (Ph ₃ P) ₂ Pt(η ² ‐C ₂ H ₄ ) mit acyclischen und cyclischen Thiosulfinaten: Platin(II)‐thiolato‐Komplexe mit Sulfenato‐Liganden. Kristallstrukturanalyse von (4‐Sulfido‐1‐butansulfenato‐ <i>S,S′</i> )‐bis(triphenylphosphan)platin(II)" @default.
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• W2045251188 doi "https://doi.org/10.1002/cber.19921250511" @default.
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