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- W2045272018 abstract "The enantioselective stereocontrolled total synthesis of aspidophytine is described. The key indole intermediate was prepared by radical cyclization of 2-alkenylphenylisocyanide, followed by Sonogashira-coupling with a highly functionalized terminal acetylene. The 11-membered cyclic amine, a precursor for the formation of the aspidosperma skeleton, was synthesized using nitrobenzenesulfonamide chemistry. After construction of the pentacyclic skeleton, the lactone ring was formed to complete the total synthesis." @default.
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- W2045272018 date "2004-03-09" @default.
- W2045272018 modified "2023-09-29" @default.
- W2045272018 title "Stereocontrolled Total Synthesis of (-)-Aspidophytine." @default.
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- W2045272018 doi "https://doi.org/10.1002/chin.200410189" @default.
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