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- W2045280869 startingPage "1348" @default.
- W2045280869 abstract "A series of alkoxo-bridged copper(II) complexes with 2-dialkylaminoethanol and 1-dialkylamino-2-propanol, [Cu2(R2NCH2CH2O)2(NCS)2] and [Cu2{R2NCH2CH(CH3)O}2(NCS)2] (R = CH3, C2H5, n-C3H7, i-C3H7), have been prepared and characterized by infrared and electronic spectroscopies, and temperature dependence of magnetic susceptibilities. The crystal structures of [Cu2{i-C3H7)2NCH2CH2O}2(NCS)2] and [Cu2{R2NCH2CH(CH3)O}2(NCS)2] (R = CH3, C2H5, n-C3H7, i-C3H7) have been determined by X-ray crystallography. The compounds are polymeric with copper atoms alternately bridged by two alkoxo oxygen atoms and two thiocyanate ions, except for [Cu2{(i-C3H7)2NCH2CH(CH3)O}2(NCS)2] which is a discrete alkoxo-bridged dinuclear molecule. The unusual magnetic properties are discussed in relation to the crystal structures." @default.
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- W2045280869 date "1994-05-01" @default.
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- W2045280869 title "X-Ray Crystal Structures and Unusual Magnetic Properties of Alkoxo-Bridged Copper(II) Complexes with 2-Dialkylaminoethanol and 1-Dialkylamino-2-propanol" @default.
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- W2045280869 doi "https://doi.org/10.1246/bcsj.67.1348" @default.
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