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• W2045291290 abstract "Reactions between Ru3(μ3-PhC2CCPh)(μ-dppm)(CO)8 (1) and SiMe3CCCCSiMe3 have given the complexes Ru2(μ-dppm){μ-C(CCPh)CPhC(SiMe3)C(CCSiMe3)}(CO)4 (3), containing the two diynes coupled in head-to-head fashion, Ru3{μ3C(SiMe3)C(CCSiMe3)C(CPh)C(CPh)C(O)}(μ-dppm)(CO)7 (4), containing a metalla–indenone ligand formed by coupling of the two diynes with CO, and Ru4(μ4-PhC2CCPh)(μ4-SiMe3C2CCSiMe3)(μ-dppm)(μ-CO)(CO)8 (6), in which the two diynes are on opposite sides of a puckered Ru4 rhomboid. Also formed were thermolysis products of 1, Ru3{μ3-CPhCHCC(C6H4)}(μ-dppm)(CO)8 (5) (previously described) and Ru4(μ4-PhC2CCPh)(μ-dppm)(CO)10 (7), the dppm-substitution product of Ru4(μ4-PhC2CCPh)(CO)12. The X-ray determined structures of 3, 6 and 7 are reported." @default.
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• W2045291290 date "1998-05-01" @default.
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• W2045291290 title "Coupling of 1,3-diynes on a triruthenium cluster: reactions of Ru3(μ3-PhC2CCPh)(μ-dppm)(CO)8 with SiMe3CCCCSiMe3" @default.
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• W2045291290 doi "https://doi.org/10.1016/s0022-328x(98)00393-3" @default.
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