FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2045313901> ?p ?o ?g. }

• W2045313901 endingPage "9259" @default.
• W2045313901 startingPage "9259" @default.
• W2045313901 abstract "Matrix isolation IR spectroscopy has been used to study the vacuum pyrolysis of 1,1,3,3-tetramethyldisiloxane (L1), 1,1,3,3,5,5-hexamethyltrisiloxane (L2) and 3H,5H-octamethyltetrasiloxane (L3) at ca. 1000 K in a flow reactor at low pressures. The hydrocarbons CH3, CH4, C2H2, C2H4, and C2H6 were observed as prominent pyrolysis products in all three systems, and amongst the weaker features are bands arising from the methylsilanes Me2SiH2 (for L1 and L2) and Me3SiH (for L3). The fundamental of SiO was also observed very weakly. By use of quantum chemical calculations combined with earlier kinetic models, mechanisms have been proposed involving the intermediacy of silanones Me2Si=O and MeSiH=O. Model calculations on the decomposition pathways of H3SiOSiH3 and H3SiOSiH2OSiH3 show that silanone elimination is favoured over silylene extrusion." @default.
• W2045313901 created "2016-06-24" @default.
• W2045313901 creator A5025777540 @default.
• W2045313901 creator A5032460989 @default.
• W2045313901 creator A5052384559 @default.
• W2045313901 creator A5068653815 @default.
• W2045313901 creator A5069306208 @default.
• W2045313901 creator A5075191912 @default.
• W2045313901 creator A5087515504 @default.
• W2045313901 date "2009-01-01" @default.
• W2045313901 modified "2023-09-25" @default.
• W2045313901 title "A mechanistic study of the low pressure pyrolysis of linear siloxanes" @default.
• W2045313901 cites W1987072076 @default.
• W2045313901 cites W1989761868 @default.
• W2045313901 cites W1992227522 @default.
• W2045313901 cites W2003143814 @default.
• W2045313901 cites W2008089727 @default.
• W2045313901 cites W2023608065 @default.
• W2045313901 cites W2026115142 @default.
• W2045313901 cites W2035395446 @default.
• W2045313901 cites W2037102824 @default.
• W2045313901 cites W2040195084 @default.
• W2045313901 cites W2053197874 @default.
• W2045313901 cites W2059247505 @default.
• W2045313901 cites W2061901307 @default.
• W2045313901 cites W2065516174 @default.
• W2045313901 cites W2071582323 @default.
• W2045313901 cites W2075104987 @default.
• W2045313901 cites W2078647531 @default.
• W2045313901 cites W2079127043 @default.
• W2045313901 cites W2081820701 @default.
• W2045313901 cites W2093892775 @default.
• W2045313901 cites W2951036237 @default.
• W2045313901 cites W4239369456 @default.
• W2045313901 doi "https://doi.org/10.1039/b910549b" @default.
• W2045313901 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19812847" @default.
• W2045313901 hasPublicationYear "2009" @default.
• W2045313901 type Work @default.
• W2045313901 sameAs 2045313901 @default.
• W2045313901 citedByCount "12" @default.
• W2045313901 countsByYear W20453139012013 @default.
• W2045313901 countsByYear W20453139012016 @default.
• W2045313901 countsByYear W20453139012017 @default.
• W2045313901 countsByYear W20453139012019 @default.
• W2045313901 countsByYear W20453139012020 @default.
• W2045313901 countsByYear W20453139012021 @default.
• W2045313901 countsByYear W20453139012022 @default.
• W2045313901 countsByYear W20453139012023 @default.
• W2045313901 crossrefType "journal-article" @default.
• W2045313901 hasAuthorship W2045313901A5025777540 @default.
• W2045313901 hasAuthorship W2045313901A5032460989 @default.
• W2045313901 hasAuthorship W2045313901A5052384559 @default.
• W2045313901 hasAuthorship W2045313901A5068653815 @default.
• W2045313901 hasAuthorship W2045313901A5069306208 @default.
• W2045313901 hasAuthorship W2045313901A5075191912 @default.
• W2045313901 hasAuthorship W2045313901A5087515504 @default.
• W2045313901 hasConcept C106487976 @default.
• W2045313901 hasConcept C121332964 @default.
• W2045313901 hasConcept C124681953 @default.
• W2045313901 hasConcept C135889238 @default.
• W2045313901 hasConcept C147597530 @default.
• W2045313901 hasConcept C147789679 @default.
• W2045313901 hasConcept C153642686 @default.
• W2045313901 hasConcept C178790620 @default.
• W2045313901 hasConcept C185592680 @default.
• W2045313901 hasConcept C191897082 @default.
• W2045313901 hasConcept C192562407 @default.
• W2045313901 hasConcept C2776758007 @default.
• W2045313901 hasConcept C2777896788 @default.
• W2045313901 hasConcept C2778958987 @default.
• W2045313901 hasConcept C2991951333 @default.
• W2045313901 hasConcept C32891209 @default.
• W2045313901 hasConcept C32909587 @default.
• W2045313901 hasConcept C36759035 @default.
• W2045313901 hasConcept C43617362 @default.
• W2045313901 hasConcept C544956773 @default.
• W2045313901 hasConcept C62520636 @default.
• W2045313901 hasConcept C97355855 @default.
• W2045313901 hasConceptScore W2045313901C106487976 @default.
• W2045313901 hasConceptScore W2045313901C121332964 @default.
• W2045313901 hasConceptScore W2045313901C124681953 @default.
• W2045313901 hasConceptScore W2045313901C135889238 @default.
• W2045313901 hasConceptScore W2045313901C147597530 @default.
• W2045313901 hasConceptScore W2045313901C147789679 @default.
• W2045313901 hasConceptScore W2045313901C153642686 @default.
• W2045313901 hasConceptScore W2045313901C178790620 @default.
• W2045313901 hasConceptScore W2045313901C185592680 @default.
• W2045313901 hasConceptScore W2045313901C191897082 @default.
• W2045313901 hasConceptScore W2045313901C192562407 @default.
• W2045313901 hasConceptScore W2045313901C2776758007 @default.
• W2045313901 hasConceptScore W2045313901C2777896788 @default.
• W2045313901 hasConceptScore W2045313901C2778958987 @default.
• W2045313901 hasConceptScore W2045313901C2991951333 @default.
• W2045313901 hasConceptScore W2045313901C32891209 @default.
• W2045313901 hasConceptScore W2045313901C32909587 @default.
• W2045313901 hasConceptScore W2045313901C36759035 @default.
• W2045313901 hasConceptScore W2045313901C43617362 @default.
• W2045313901 hasConceptScore W2045313901C544956773 @default.

• next