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- W2045332602 abstract "Treatment of (PPh2)2C2B10H10 with gold(I)complexes [AuX(tht)](tht = tetrahydrothiophene, X = Cl or C6F5) gives two-co-ordinate [(AuX)2{(PPh2)2C2B10H10}] or three-co-ordinate [AuX{(PPh2)2C2B10H10}] species. Other three-co-ordinate compounds have been prepared starting from [Au(tht)L]ClO4(L = tht, PR3, or ylide) by reaction with the diphosphine. Substitution of tht in [Au(tht){(PPh2)2C2B10H10}]ClO4 affords [AuL{(PPh2)2C2B10H10}]ClO4 where, depending on the ligand, three-co-ordinate (L = SPPh3, AsPh3, or C5H4NSH) or four-co-ordinate complexes [L = 1,10-phenanthroline or (PPh2)2C2B10H10] can be synthesised. The bis-chelated gold(I) phosphine complex [Au{(PPh2)2C2B10H10}2]ClO4 has been isolated. The crystal structure of [Au(PPh3){(PPh2)2C2B10H10}]ClO4·CH2Cl2 has been established by X-ray crystallography: monoclinic space group P21/n, a= 11.760(3), b= 20.290(5), c= 21.375(6)Å, β= 105.10(2)°, Z= 4, R= 0.032. The gold atom exhibits trigonal-planar co-ordination, by three phosphorus atoms with Au–P 2.318(1), 2.405(1) and 2.417(1)Å(the longer bonds are to the diphosphine)." @default.
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- W2045332602 date "1992-01-01" @default.
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- W2045332602 title "Two-, three- and four-co-ordinate gold(I) complexes of 1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane" @default.
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- W2045332602 doi "https://doi.org/10.1039/dt9920001601" @default.
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