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- W2045334092 abstract "Abstract Novel C(CH3)2 bridged molecules, (CH3)2C(C5H4)2M(CH3)2, M = Ti, Zr, were synthesized. The structures of both molecules were determined by X-ray diffraction analysis. For the Ti compound: crystals, monoctinic; space group, P21, / m, a = 7.196(4), b = 10.227(1), c = 8.941(3) A, γ = 89.95°. For Zr compound: crystals, monoclinic; space group P21 / m, a = 7.333(4), b = 10.429(3), c = 9.031(6) A, γ = 89.98°. Both molecules are characterized, as expected, by significant intramolecular tension resulting in obvious distortion of the sandwich moiety." @default.
- W2045334092 created "2016-06-24" @default.
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- W2045334092 date "1992-02-01" @default.
- W2045334092 modified "2023-09-27" @default.
- W2045334092 title "ansa-Metallocene derivatives of TiIV and ZrIV with the shortest C(CH3)2 bridge" @default.
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- W2045334092 doi "https://doi.org/10.1016/0022-328x(92)83458-t" @default.
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