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• W2045335416 startingPage "9723" @default.
• W2045335416 abstract "Fine-tuned control over the donor strength in a series of trannulenes-based donor−acceptor ensembles is used to alter the deactivation path of the photoexcited-state chromophore and to modulate the rates of intramolecular electron transfer. For the first time, a detailed analysis of emission spectra, time-dependent spectroscopic measurements, and electrochemistry prove spectroscopically and kinetically that trannulenes can serve, in a manner similar to C60 and C60 monoadducts, as both electron and also as energy acceptor in donor−acceptor ensembles, producing widely different electron-transfer regimes. This investigation also shows that the integration of trannulenes, as a versatile electron-acceptor building block, consistently produces charge recombination in the inverted Marcus region." @default.
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• W2045335416 date "2005-10-08" @default.
• W2045335416 modified "2023-09-23" @default.
• W2045335416 title "Fluorinated Fullerenes: Sources of Donor−Acceptor Dyads with [18]Trannulene Acceptors for Energy- and Electron-Transfer Reactions" @default.
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• W2045335416 doi "https://doi.org/10.1021/jp053295h" @default.
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