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- W2045347792 abstract "Nitroxide-mediated solution and precipitation polymerizations of styrene in toluene and supercritical carbon dioxide (scCO2), respectively, using the nitroxides N-tert-butyl-N-[1-diethylphosphono-(2,2-dimethylpropyl)]nitroxide (SG1) and 2,2,5-trimethyl-4-phenyl-3-azahexane-3-nitroxide (TIPNO) are presented. Solution polymerizations are compared with simulations using PREDICI software, revealing that differences in the polymerization behaviours between the SG1- and TIPNO-mediated systems cannot be rationalized based on literature rate coefficients and the ideal mechanism for nitroxide-mediated polymerization. Nitroxide and monomer partitioning between the polymer particles and the continuous phase play important roles in the precipitation polymerizations in scCO2. Loss of control (broader molecular weight distributions) as a result of nitroxide partitioning is accentuated at low monomer loading, and is significantly more pronounced for TIPNO than SG1. However, at higher monomer loading the level of control was superior in scCO2 compared to in the corresponding solution polymerizations for both nitroxides, most likely caused by an increase in the number of activation-deactivation cycles experienced by any given chain during its growth." @default.
- W2045347792 created "2016-06-24" @default.
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- W2045347792 date "2008-12-01" @default.
- W2045347792 modified "2023-10-14" @default.
- W2045347792 title "Nitroxide-mediated precipitation polymerization of styrene in supercritical carbon dioxide: Effects of monomer loading and nitroxide partitioning on control" @default.
- W2045347792 cites W1964204497 @default.
- W2045347792 cites W1964805700 @default.
- W2045347792 cites W1966863664 @default.
- W2045347792 cites W1968078903 @default.
- W2045347792 cites W1968922359 @default.
- W2045347792 cites W1976233240 @default.
- W2045347792 cites W1978520016 @default.
- W2045347792 cites W1983419216 @default.
- W2045347792 cites W1984480827 @default.
- W2045347792 cites W1984620994 @default.
- W2045347792 cites W1986573296 @default.
- W2045347792 cites W1986995988 @default.
- W2045347792 cites W1992679856 @default.
- W2045347792 cites W1993324063 @default.
- W2045347792 cites W1993758718 @default.
- W2045347792 cites W2000350896 @default.
- W2045347792 cites W2000764933 @default.
- W2045347792 cites W2001898017 @default.
- W2045347792 cites W2010140872 @default.
- W2045347792 cites W2013523409 @default.
- W2045347792 cites W2015077402 @default.
- W2045347792 cites W2015103875 @default.
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- W2045347792 cites W2020319168 @default.
- W2045347792 cites W2027975013 @default.
- W2045347792 cites W2029275892 @default.
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- W2045347792 doi "https://doi.org/10.1016/j.eurpolymj.2008.09.020" @default.
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