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- W2045348003 abstract "Abstract The magnetic characterization of the LaNi1−xSbxO3 (0≤x≤ 1 3 ) perovskite-like system is reported. These compounds can be regarded as being derived from LaNiO3 by partial substitution of Ni3+ by Sb5+ cations with the concomitant partial reduction of Ni3+ to Ni2+. Formally, for x=0 only Ni3+ is present, whereas for x= 1 3 Ni cations are stabilized as Ni2+. Magnetic susceptibility measurements show that a transition from a Pauli paramagnetic behaviour (x=0.05) to complex magnetic interactions takes place in this system. The nature of such interactions is interpreted as antiferromagnetic with an important canting of the spin arrangement, giving rise to a noticeable ferromagnetic component. These results have been qualitatively confirmed using the EPR technique." @default.
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- W2045348003 date "1997-06-01" @default.
- W2045348003 modified "2023-09-29" @default.
- W2045348003 title "Magnetic characterization of the LaNi1−xSbxO3 perovskite-like system" @default.
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- W2045348003 doi "https://doi.org/10.1016/s0925-8388(96)02870-8" @default.
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