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- W2045352616 abstract "Abstract The reaction of [OsCl 2 (PPh 3 ) 3 ] ( 1 ) with i Pr 2 PCH 2 CH 2 NMe 2 in 2‐propanol under reflux affords the Fischer‐type aminocarbene complex cis , cis ‐[OsCl 2 {κ 2 ( C , P )‐CHN(CH 3 )CH 2 CH 2 P i Pr 2 }{κ 2 ( P , N )‐ i Pr 2 PCH 2 CH 2 NMe 2 }] ( 2 ) by double C–H activation of one NCH 3 group. While treatment of 2 with phenylacetylene leads to the vinylidene complex cis , trans ‐[OsCl 2 (C=CHPh){κ 2 ( C , P )‐CHN(CH 3 )CH 2 CH 2 P i Pr 2 }{κ( P )‐ i Pr 2 PCH 2 CH 2 NMe 2 }] ( 3 ) by partial opening of the P , N ‐chelate bond, the reaction of 2 with CO and CN t Bu gives rise to ionic compounds of type [OsCl(L){κ 2 ( C , P )‐CHN(CH 3 )CH 2 CH 2 P i Pr 2 }{κ 2 ( P , N )‐ i Pr 2 PCH 2 CH 2 OMe}]Cl ( 4 : L = CO, 5 : L = CN t Bu) by substitution of one chloro ligand. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)" @default.
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- W2045352616 date "2009-10-20" @default.
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- W2045352616 title "Synthesis and Reactivity of an Aminocarbene Osmium Complex Formed by Double C–H Activation of a NCH <sub>3</sub> Unit" @default.
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- W2045352616 doi "https://doi.org/10.1002/ejic.200900759" @default.
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