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• W2045359928 startingPage "14264" @default.
• W2045359928 abstract "The reaction of the bulky bis(imidazolin-2-iminato) ligand precursor (1,2-(LMesNH)2-C2H4)[OTs]2 (12+ 2[OTs]−; LMes=1,3-dimesityl imidazolin-2-ylidene, OTs=p-toluenesulfonate) with lithium borohydride yields the boronium dihydride cation (1,2-(LMesN)2-C2H4)BH2[OTs] (2+ [OTs]−). The boronium cation 2+ [OTs]− reacts with elemental sulfur to give the thioxoborane salt (1,2-(LMesN)2-C2H4)BS[OTs] (3+ [OTs]−). The hitherto unknown compounds 12+ 2[OTs]−, 2+ [OTs]−, and 3+ [OTs]− were fully characterized by spectroscopic methods and single-crystal X-ray diffraction. Moreover, DFT calculations were carried out to elucidate the bonding situation in 2+ and 3+. The theoretical, as well as crystallographic studies reveal that 3+ is the first example for a stable cationic complex of three-coordinate boron that bears a BS double bond." @default.
• W2045359928 created "2016-06-24" @default.
• W2045359928 creator A5027134195 @default.
• W2045359928 creator A5067961961 @default.
• W2045359928 creator A5075734962 @default.
• W2045359928 date "2014-10-16" @default.
• W2045359928 modified "2023-10-02" @default.
• W2045359928 title "Isolation of a Three-Coordinate Boron Cation with a Boron-Sulfur Double Bond" @default.
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• W2045359928 cites W1982458575 @default.
• W2045359928 cites W1985495475 @default.
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• W2045359928 cites W1999145802 @default.
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• W2045359928 doi "https://doi.org/10.1002/anie.201407809" @default.
• W2045359928 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25323781" @default.
• W2045359928 hasPublicationYear "2014" @default.
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