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- W2045361800 abstract "Die hydrocarbonylierende Cyclisierung von 1,4-Dienen 16, 27 zu Cyclopentanonen 17, 28 wurde mit dem Ziel der Synthese des Cuparengerüsts auf ihre Regio- und Stereoselektivität hin untersucht und die Tolerierbarkeit von Arylgruppen bei dieser Cyclisierung getestet. Darauf aufbauend wurde eine neue Synthese des (±)-(α)-Cuparenons (29c) entwickelt. Regio- and Stereoselectivity of the Hydrocarbonylating Cyclization of 1,4-Dienes with Carbon Monoxide: Synthesis of (±)-(α)-Cuparenone Directed towards the synthesis of the cuparene skeleton the hydrocarbonylating cyclization of 1,4-dienes 16, 27 to form cyclopentanones 17, 28 was tested for its regio- and stereoselectivity as well as the toleration of aryl groups in this cyclization method. Based on these results a new synthesis of (±)-(α)-cuparenone (29c) is developed." @default.
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- W2045361800 date "1985-02-01" @default.
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- W2045361800 title "Zur Regio‐ und Stereoselektivität der hydrocarbonylierenden Cyclisierung von 1,4‐Dienen mit Kohlenmonoxid: Synthese des (±)‐(α)‐Cuparenons" @default.
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- W2045361800 doi "https://doi.org/10.1002/cber.19851180240" @default.
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