Matches in SemOpenAlex for { <https://semopenalex.org/work/W2045370377> ?p ?o ?g. }
- W2045370377 endingPage "170" @default.
- W2045370377 startingPage "162" @default.
- W2045370377 abstract "The resistivity ϱ(T) and thermopower S(T) of the 2212-structure-type Bi8Sr8−xCa4+xCu9O33+E−δ series of solid solutions with x=0, 1, 2, 3 and 4 have been examined. The compounds sintered in air show an excess of oxygen content whose maximum E=1.25 is found for x=0 with a tendency to decrease with increasing x. Deoxygenation of x=2 solution (vacuum at elevated temperatures) by δ > 1.4 leads to structural degradation. The as-sintered solutions are superconducting below Tc≈69–74 K. The latter can be optimized with respect to oxygen content. For x=2 and δ≈0.1 the Tc increases to 94 K. Both S(T) and ϱ(T) vary monotonically with δ from metallic to nonmetallic-type behavior. The solutions become nonmetallic and nonsuperconducting at δ⩾0.46 (x=2). The substitution parameter (x) affects the resistivity and thermopower in the same way as δ but by one order of magnitude weaker in comparison with changes of the oxygen-content: - (ΔS/ΔE)T=250 K=11±3 μ VK−1 per ox at. (oxygen atom) per f.u. (formula unit), (ΔS/Δδ)T=250 K=96±15 μ VK−1 per ox. at. per f.u." @default.
- W2045370377 created "2016-06-24" @default.
- W2045370377 creator A5016345085 @default.
- W2045370377 creator A5024026952 @default.
- W2045370377 creator A5075990597 @default.
- W2045370377 creator A5080884030 @default.
- W2045370377 date "1992-07-01" @default.
- W2045370377 modified "2023-10-02" @default.
- W2045370377 title "The effect of isoelectronic cation substitution and deoxygenation of Bi8Sr8−xCa4+xCu9O33+E−δ superconductors on the thermopower and resistivity" @default.
- W2045370377 cites W1626040846 @default.
- W2045370377 cites W1963618215 @default.
- W2045370377 cites W1965002467 @default.
- W2045370377 cites W1977417852 @default.
- W2045370377 cites W1981043981 @default.
- W2045370377 cites W1995099510 @default.
- W2045370377 cites W2002932618 @default.
- W2045370377 cites W2004249225 @default.
- W2045370377 cites W2022620806 @default.
- W2045370377 cites W2034330495 @default.
- W2045370377 cites W2042624846 @default.
- W2045370377 cites W2057821993 @default.
- W2045370377 cites W2092164850 @default.
- W2045370377 cites W2121583153 @default.
- W2045370377 doi "https://doi.org/10.1016/0921-4534(92)90280-p" @default.
- W2045370377 hasPublicationYear "1992" @default.
- W2045370377 type Work @default.
- W2045370377 sameAs 2045370377 @default.
- W2045370377 citedByCount "8" @default.
- W2045370377 crossrefType "journal-article" @default.
- W2045370377 hasAuthorship W2045370377A5016345085 @default.
- W2045370377 hasAuthorship W2045370377A5024026952 @default.
- W2045370377 hasAuthorship W2045370377A5075990597 @default.
- W2045370377 hasAuthorship W2045370377A5080884030 @default.
- W2045370377 hasConcept C112625512 @default.
- W2045370377 hasConcept C113196181 @default.
- W2045370377 hasConcept C115624301 @default.
- W2045370377 hasConcept C121332964 @default.
- W2045370377 hasConcept C134306372 @default.
- W2045370377 hasConcept C138999460 @default.
- W2045370377 hasConcept C149635348 @default.
- W2045370377 hasConcept C161790260 @default.
- W2045370377 hasConcept C178790620 @default.
- W2045370377 hasConcept C185592680 @default.
- W2045370377 hasConcept C191897082 @default.
- W2045370377 hasConcept C192562407 @default.
- W2045370377 hasConcept C26873012 @default.
- W2045370377 hasConcept C2778152352 @default.
- W2045370377 hasConcept C2779778602 @default.
- W2045370377 hasConcept C33923547 @default.
- W2045370377 hasConcept C41008148 @default.
- W2045370377 hasConcept C540031477 @default.
- W2045370377 hasConcept C54101563 @default.
- W2045370377 hasConcept C544153396 @default.
- W2045370377 hasConcept C58312451 @default.
- W2045370377 hasConcept C62520636 @default.
- W2045370377 hasConcept C69990965 @default.
- W2045370377 hasConcept C8010536 @default.
- W2045370377 hasConcept C88260341 @default.
- W2045370377 hasConceptScore W2045370377C112625512 @default.
- W2045370377 hasConceptScore W2045370377C113196181 @default.
- W2045370377 hasConceptScore W2045370377C115624301 @default.
- W2045370377 hasConceptScore W2045370377C121332964 @default.
- W2045370377 hasConceptScore W2045370377C134306372 @default.
- W2045370377 hasConceptScore W2045370377C138999460 @default.
- W2045370377 hasConceptScore W2045370377C149635348 @default.
- W2045370377 hasConceptScore W2045370377C161790260 @default.
- W2045370377 hasConceptScore W2045370377C178790620 @default.
- W2045370377 hasConceptScore W2045370377C185592680 @default.
- W2045370377 hasConceptScore W2045370377C191897082 @default.
- W2045370377 hasConceptScore W2045370377C192562407 @default.
- W2045370377 hasConceptScore W2045370377C26873012 @default.
- W2045370377 hasConceptScore W2045370377C2778152352 @default.
- W2045370377 hasConceptScore W2045370377C2779778602 @default.
- W2045370377 hasConceptScore W2045370377C33923547 @default.
- W2045370377 hasConceptScore W2045370377C41008148 @default.
- W2045370377 hasConceptScore W2045370377C540031477 @default.
- W2045370377 hasConceptScore W2045370377C54101563 @default.
- W2045370377 hasConceptScore W2045370377C544153396 @default.
- W2045370377 hasConceptScore W2045370377C58312451 @default.
- W2045370377 hasConceptScore W2045370377C62520636 @default.
- W2045370377 hasConceptScore W2045370377C69990965 @default.
- W2045370377 hasConceptScore W2045370377C8010536 @default.
- W2045370377 hasConceptScore W2045370377C88260341 @default.
- W2045370377 hasIssue "1-2" @default.
- W2045370377 hasLocation W20453703771 @default.
- W2045370377 hasOpenAccess W2045370377 @default.
- W2045370377 hasPrimaryLocation W20453703771 @default.
- W2045370377 hasRelatedWork W1986506802 @default.
- W2045370377 hasRelatedWork W2041597509 @default.
- W2045370377 hasRelatedWork W2043792189 @default.
- W2045370377 hasRelatedWork W2045370377 @default.
- W2045370377 hasRelatedWork W2072628683 @default.
- W2045370377 hasRelatedWork W2075148648 @default.
- W2045370377 hasRelatedWork W2367928675 @default.
- W2045370377 hasRelatedWork W2412374185 @default.
- W2045370377 hasRelatedWork W3022965329 @default.
- W2045370377 hasRelatedWork W2157150797 @default.
- W2045370377 hasVolume "198" @default.