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- W2045372214 abstract "Boulton, J.R. and Stein, F.P., 1993. The constant pressure heat capacity of supercritical carbon dioxide-methanol and carbon dioxide-ethanol co-solvent mixtures. Fluid Phase Equilibria, 91: 159-176. The constant-pressure heat capacity ratio, CPHP/Catm (where CPHP is the heat capacity at high pressure and CP1 atm the heat capacity at 1 atm) was measured for binary mixtures of carbon dioxide-methanol and carbon dioxide-ethanol. The data were obtained at pressures up to 82 bar for isotherms ranging from 320.0 to 333.2 K and are estimated to be accurate to ± 1.0% over most of the composition-temperature-pressure range. The methanol and ethanol co-solvent concentrations ranged from 0.77 to 1.88 mol%. No maximum in the heat capacity was encountered. The largest heat capacity ratio observed was 4.396 for a 1.27 mol% methanol in carbon dioxide mixture at 320.0 K and 82 bar. A model to correlate the heat capacity was developed." @default.
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- W2045372214 date "1993-11-01" @default.
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- W2045372214 title "The constant pressure heat capacity of supercritical carbon dioxide-methanol and carbon dioxide-ethanol co-solvent mixtures" @default.
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- W2045372214 doi "https://doi.org/10.1016/0378-3812(93)85086-2" @default.
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