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• W2045386314 abstract "The surface chemistry of iodobenzene (C6H5I) on Pt(111) has been studied by temperature-programmed desorption (TPD), X-ray photoelectron spectroscopy (XPS), high resolution electron energy loss spectroscopy (HREELS) and isotopic labeling. XPS results show that for the first layer CI bond scission commences at 175 K. The phenyl fragment (C6H5) left after CI bond cleavage loses a hydrogen and forms an ortho-C6H4 (benzyne) intermediate. Upon further annealing, the benzyne is rehydrogenated and forms benzene (C6H6), with hydrogen supplied by the decomposition of other benzyne species. Formation of benzyne involves a change in the adsorption geometry of the adsorbate adlayer, which consequently opens new decomposition sites on the Pt(111) and allows the dissociation of approximately 70% of the second layer to occur. The dissociation of the second layer leads to additional C6H6 formation via a coupling reaction of a phenyl fragment from the second layer and a surface hydrogen. The role that iodine plays on these reaction pathways and the implications of these results to the surface chemistry of benzene on transition metal surfaces are discussed." @default.
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• W2045386314 date "2000-02-01" @default.
• W2045386314 modified "2023-09-25" @default.
• W2045386314 title "The thermal chemistry of iodobenzene on Pt(111)" @default.
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• W2045386314 doi "https://doi.org/10.1016/s0039-6028(99)01150-4" @default.
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