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• W2045391502 abstract "The dependence of electrocatalytic effects on the structural properties of two-dimensional (2-D) metal adsorbates formed by underpotential deposition (UPD) of Pb, Tl and Bi on gold and silver single crystal faces of (111), (110) and (100) orientation is demonstrated for various electro-reduction reactions in acid solutions. Positive and negative electrocatalytic effects are observed depending on the metal substrate/adsorbate combination, on the degree of metal adsorbate coverage as well as on the type of redox reaction. Specificity of bond formations of reactants, intermediates and/or products with respect to the structural arrangement of the adatoms may explain the observed dependence on the crystallographic orientation of the substrate." @default.
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• W2045391502 creator A5041699777 @default.
• W2045391502 date "1986-08-01" @default.
• W2045391502 modified "2023-09-26" @default.
• W2045391502 title "Surface structural effects in electrocatalysis" @default.
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• W2045391502 doi "https://doi.org/10.1016/0013-4686(86)80004-4" @default.
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