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- W2045394534 abstract "The thermal decomposition of tribochemically activated Al2(SO4)3·xH2O was studied by TG, DTA and EMF methods. For some of the intermediate solids, X-ray diffraction and IR-spectroscopy were applied to learn more about the reaction mechanism. Thermal and EMF studies confirmed that, even after mechanical activation of Al2(SO4)3·xH2O, Al2O(SO4)2 is formed as an intermediate. Isothermal kinetic experiments demonstrated that the thermochemical sulphurization of inactivated Al2(SO4)3·xH2O has an activation energy of 102.2 kJ·mol−1 in the temperature range 850–890 K. The activation energy for activated Al2(SO4)3·xH2O in the range 850–890 K is 55.0 kJ·mol−1. The time of thermal decomposition is almost halved when Al2(SO4)3·xH2O is activated mechanically. The results permit conclusions concerning the efficiency of the tribochemical activation of Al2(SO4)3·xH2O and the chemical and kinetic mechanisms of the desulphurization process." @default.
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- W2045394534 date "1995-01-01" @default.
- W2045394534 modified "2023-09-27" @default.
- W2045394534 title "Tribochemistry and kinetics of Al2(SO4)3·xH2O decomposition" @default.
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- W2045394534 doi "https://doi.org/10.1007/bf02636005" @default.
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