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- W2045396007 abstract "Abstract The growth rate of the crystalline complex PEO 3 NaSCN from an undercooled liquids is used to measure the mutual diffusion coefficient of NaSCN and poly (ethylene oxide) (PEO). Useful results were obtained between 65°C and 95°C for complexes containing 11 mole% NaSCN in PEO with molecular weights ranging from 3500 to 600000g/mole. The observed diffusivity is in the range (0.6−3.2)×10 −8 cm 2 /s and is independent of polymer molecular weight, indicating that the polymer is effectively static and that the growth rate method yields the chemical diffusion coefficient of Na and SCN species. The absolute values of D compare well with those from radioactive tracer studies." @default.
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- W2045396007 date "1991-04-01" @default.
- W2045396007 modified "2023-09-24" @default.
- W2045396007 title "Ion diffusivity from the growth rate of crystalline complex PEO3NaSCN" @default.
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- W2045396007 doi "https://doi.org/10.1016/0167-2738(91)90154-4" @default.
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