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- W2045405554 abstract "Abstract The interactions of some simple amino acids (AA) like alanine, valine and leucine with drug ampicillin (AMP) as a function of temperature have been investigated by combination of volumetric and acoustic methods. Densities and speeds of sound of alanine, valine and leucine in aqueous solutions of ampicillin have been measured at T = (305.15, 310.15 and 315.15) K and atmospheric pressure. The apparent molar volume (Vϕ), the partial molar volume (Vϕ0), limiting apparent molar expansibility (ϕE0) and standard partial molar volumes of transfer (ΔVϕ⁰) for amino acids from water to aqueous ampicillin solutions have been calculated from density data. Partial molar adiabatic compressibility (Kϕ,s) and partial molar adiabatic compressibility of transfer (ΔKϕ,S0) have been calculated from speed of sound data. The pair and triplet interaction coefficients have been calculated from both the properties. The results have been explained on the basis of competing patterns of interactions of co-solvent and the solute." @default.
- W2045405554 created "2016-06-24" @default.
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- W2045405554 date "2012-09-01" @default.
- W2045405554 modified "2023-09-24" @default.
- W2045405554 title "Investigation on molecular interaction of amino acids in antibacterial drug ampicillin solutions with reference to volumetric and compressibility measurements" @default.
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- W2045405554 doi "https://doi.org/10.1016/j.molliq.2012.07.008" @default.
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