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• W2045431035 abstract "Densities, ρ, ultrasonic speeds, u, and viscosities, η, of aqueous-glucose (2.5, 5, 10, 15 and 20% of glucose, w/w in water) and of solutions of l-methionine in four aqueous-glucose solvents were measured at 293.15, 298.15, 303.15, 308.15, 313.15, and 318.15 K. From these experimental data, apparent molar volume, Vϕ limiting apparent molar volume, V°ϕ and the slope, Sv, apparent molar compressibiliity, Ks,ϕ, limiting apparent molar compressibility, K°s,ϕ and the slope, Sk, transfer volume, V°ϕ,tr, transfer compressibility, K°s,ϕ,tr, Falkenhagen coefficient, A, Jones–Dole coefficient, B, free energy of activation of viscous flow per mole of solvent, Δμ1°# and per mole of solute, Δμ2°# were calculated. The results are interpreted in terms of solute–solvent and solute–solute interactions in these systems. It is observed that there exist strong solute–solvent interactions in these systems, which increase with increase in glucose concentration. It is observed that l-methionine act as structure-breaker in aqueous-glucose solvents. The thermodynamics of viscous flow has also been discussed." @default.
• W2045431035 created "2016-06-24" @default.
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• W2045431035 date "2011-04-01" @default.
• W2045431035 modified "2023-09-30" @default.
• W2045431035 title "Volumetric, ultrasonic and viscometric behavior of l-methionine in aqueous-glucose solutions at different temperatures" @default.
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• W2045431035 doi "https://doi.org/10.1016/j.molliq.2011.01.010" @default.
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